Correction: Dehydrocoupling of phosphine–boranes using the [RhCp*Me(PMe3)(CH2Cl2)][BArF4] precatalyst: stoichiometric and catalytic studies

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Stoichiometric and catalytic Sn-mediated dehydrocoupling of primary phosphines.

The room-temperature reactions of stannocene, Cp*(2)Sn, with a range of primary phosphines, RPH(2), result in diphosphanes [RP(H)P(H)R]. The reactions involving Cp*(2)SnCl(2), however, result in catalytic dehydrocoupling; the first example of main group metal catalysed dehydrocoupling to be identified.

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ژورنال

عنوان ژورنال: Chemical Science

سال: 2016

ISSN: 2041-6520,2041-6539

DOI: 10.1039/c6sc90014c